Barca were stunned by Athletic Bilbao as the new season got under way last Friday, going down 1-0 to Aritz Aduriz’s late winner.
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Now Ernesto Valverde’s side will be looking to bounce back in their first home clash of the campaign.
Real Betis had ex-Everton goalkeeper Joel Robles sent off in the eighth minute as they lost to Real Valladolid in their first game of the new term.