The Manchester United attacker sent former Arsenal team-mate David Ospina the wrong way in the shoot-out, as the holders won 5-4 and set up a meeting with either Uruguay or Peru, who play on Saturday.
Sam Matterface and Danny Mills are full of praise for the England's Ellen White
Despite his struggles for his club last season, the 30-year-old has found form in the South American competition, netting in wins over Ecuador and Japan.
Chile, the two-time winners, could have had the match won in normal time, but VAR ruled out goals for them in either half and after extra-time failed to produce a breakthrough, the game went to penalties.
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