Following a goalless first-half in their Euro 2020 qualifier, Ramos opened the scoring from the penalty spot on 65 minutes.
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Spain were awarded another penalty with five minutes remaining, but rather than taking the chance to double his goal tally, Ramos passed on the spot kit to Morata instead.
The Chelsea striker, who is on loan at Atletico Madrid until the end of next season, looked genuinely surprised when his skipper passed him the ball.
Morata made no mistake from 12 yards, as he netted to make it three international goals in 2019.
Substitute Mikel Oyarzabal added a third two minutes later.